Type 434 is one of the most used of the nonhardenable ferritic stainless steels. Ati 439 stainless steel was developed in the 1950s for use in directfired hot water heater tanks, an application requiring good weldability and stress corrosion cracking resistance, and was successfully employed in potable waters throughout the united states. Most stainless steels have relatively high strength, good corrosion resistance, and ductility. The actual pitting corrosion phenomenon is shown on propeller shaft of high speed craft, and the pit depth was measured with dial. The effect of salt loading on chlorideinduced stress. External chloride stress corrosion cracking ecscc of insulated austenitic stainless steels e. Stress corrosion cracking of duplex stainless steel scc stress corrosion cracking is a form of corrosion which occurs with a particular combination of factors. Stainless steel for hardness and corrosion resistance. Oct 21, 2019 chloride stress corrosion cracking cscc is a type of intergranular corrosion.
Ak steel 434 is a modification of type 430, the addition of molybdenum increases this alloys corrosion resistance and its attack from many deicing chemicals. Stainless steel alloy an overview sciencedirect topics. Pitting corrosion of stainless steels, on the other hand, occurs in solutions of all halides except f. Corrosion of common alloys in dry chlorine cl2 penflex. Stress corrision cracking is a relatively rare form of corrosion, which requires a specific combination of tensile stress, temperature and corrosive species, often the chloride ion, for it to occur. Keep in mind that moisture will greatly accelerate attack of any of these materials with the additional danger of scc stress corrosion cracking of stainless steel. Zaki ahmad, in principles of corrosion engineering and corrosion control, 2006 a stress corrosion cracking of ferritic steels in chloride media. Stainless steel s fine layer of chromium oxide has natural techniques to selfrepair when breached or broken. Stress corrosion cracking of type 430 ferritic stainless steel in chloride and sulfate solutions r. Stress corrosion cracking facts and how to reduce the.
This identifies the specific chemistry that is desired. High purity ferritic stainless steels are subjected to scc in boiling 30% sodium hydroxide in tests exceeding h and in 42% mgcl 2 in a sensitized condition. Jan 08, 2002 while stainless steels are often used for their corrosion resistance, they do in fact suffer from corrosion under certain circumstances. Stress corrosion cracking scc is a frequently occurring type of steel.
A complete, uptodate introduction to corrosion of stainlesssteels and metallurgical factors this fully updated second editionof corrosion of stainless steels covers the tremendous advancesmade with stainless steels in recent decades, includingapplications in many new areasfrom marine technologies andoffshore oil production to power plants and the kitchen sink. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. Austenitic steel is sensitive to this type of corrosion above 60c in the presence of dissolved oxygen. The effect of cold work on stress corrosion cracking of type 302 austenitic stainless steel wire exposed to boiling 154 c, 309 f 42 weightpercent aqueous magnesium chloride solution was determined. Corrosion of unprotected carbon steel occurs even inside reinforced. Stress corrosion cracking of type 430 ferritic stainless. Localized corrosion and stress corrosion cracking of stainless steels. Duplex stainless steels can be used to avoid the stress corrosion cracking associated with austenitic stainless steels.
It compares the types, grades, chemistries, finishes and. Corrosion behaviour of type 316l stainless steel in hot. Grade 434 stainless steel contains added molybdenum to increase its corrosion resistance. Understanding and avoiding intergranular stress corrosion cracking of welded supermartensitic stainless steel. Ferritic stainless steel properties and applications. Paper presented at corrosion 2007, paper 07094, nashville, tennessee, 1115 march 2007. The pitting corrosion resistance of stainless steels is estimated by the pitting resistance equivalent number. Ferritic stainless steel forms one of the four stainless steel families, the other three being. Corrosion of stainless steel by hot caustic research using solutions of chemically pure caustic sodium hydroxide naoh led to the development of a diagram that attempts to delineate the param eters of concentration and tem perature governing stress corrosion cracking scc of type.
Ferritic grades have been developed to provide a group of stainless steel to resist corrosion and oxidation, while being highly resistant to stress corrosion cracking. For those seeking alternative grades to the 430 stainless steel, possible options include 430f, 434. Martensitic stainless steel aisi 434 boltport fasteners. It is used in food equipment, chemical equipment and architectural applications. It can be detrimental to austenitic stainless steels, one of the main reasons these steels are not considered a cureall for corrosion problems. Ricker, national institute of standards and technology stresscorrosion cracking scc is a term used to describe service failures in engineering materials that occur by slow, environmentally induced crack propagation. Past researched about scc of 310s primarily focus on the corrosion mechanism and influence of temperature and corrosive media, but few studies concern the combined influence of temperature, pressure and chloride. The most common environmental exposure condition responsible for scc of stainless steels is the presence of chlorides. Like other highsulphur free machining grades 430f has much reduced resistance to pitting and crevice corrosion compared to its nonfree machining equivalent. Grade 430 is a ferritic, straight chromium, nonhardenable grade, combining good corrosion resistance and formability characteristics with useful mechanical properties. The corrosion of stainless steels in fluoridecontaining process waste indicated type 316 elc stainless steel as likely material for tank construction. Prevention of external chloride stress corrosion cracking of. Design guidelines for the selection and use of stainless steel nidl distributed by.
Stress corrosion cracking in duplex stainless steel. The micrograph on the left x300 illustrates scc in a 316 stainless steel chemical processing piping system. Pdf chloride induced stress corrosion cracking of type 304. Stainless steel 430 stainless steel supplier malaysia. Xox corrosion inhibitor can neutralize the effects of the chlorides. The effect of salt loading on chlorideinduced stress corrosion cracking in 304 l was studied at atmospheric pressure. Aisi 304 stainless steel ss is one of the candidate materials used for dry storage canisters of spent nuclear fuel as an interim storage measure before final disposal 1,2. Deterioration by clscc can lead to failures that have the potential to release stored energy andor hazardous substances. This mode of attack is termed stress corrosion cracking scc.
However, 430 grade stainless steel has a very high stress corrosion cracking resistance and. Known for their good ductility, resistance to corrosion and stress corrosion cracking, ferritic steels are commonly used in automotive applications, kitchenware, and industrial equipment. Ferritic stainless steel are magnetic and cannot be hardened by heat treatment and are always used in the annealed condition. Stainless steels sss may suffer scc when three critical conditions occur simultaneously. It compares the types, grades, chemistries, finishes and applications of stainless steels produced by ak steel.
A cracked nozzle sleeve stub from a chemical processing vessel of the proprietary vaporizer system was analyzed to determine the cause of cracking. The higher alloyed duplex stainless steel alloys, ones with significant molybdenum and. Analysis of corroded stainless steel bolts summary. The following table shows the chemical composition of grade 434 stainless steel. Stainless steels for corrosive environments notz group. Ams 5503, astm a240 434 alloy description alloy 434 is one of the most widely used of the ferritic stainless steels. The most common type of stress corrosion cracking in stainless steels occurs in chloride environments, which will. Type 434 stainless steel alloys are ductile and do not workharden readily. Ferritic steels, types 430 and 434, are resistant to scc in mgcl 2 at 140c. Ferritic stainless steel 434 plate s43400 ferritic stainless steel. The corrosion behaviour of type 316l stainless steel in aqueous 3050 wt%.
Selecting the right stainless steel for your application can be perplexing. The duplex stainless steels were developed to exhibit comparable general corrosion resistance as 316ss, but with reduced susceptibility to chloride stress corrosion cracking. The effect of cold work on the stresscorrosion cracking. Wr1200 is xox corrosion inhibitor, a distinctive formula and process that inhibits corrosion to the outside surfaces of pipe and equipment, especially stress corrosion cracking of austenitic stainless steel. Chromium forms a surface film of chromium oxide to make the stainless steel corrosion resistant. Austenitic stainless steels are the most specified grades produced because of their. The chemical compositions of 434 ferritic stainless steel and cecontaining steels. Effects of temperature and pressure on stress corrosion. Postweld heat treatment to avoid intergranular stress corrosion cracking of supermartensitic stainless steels. To qualify insulation, the manufacturer or supplier must. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. But there are ways to mninimize the risk of corrosion. It is has performance and chemistry similar to that of 430 stainless steel. Different kinds of corrosion on stainless steel montanstahl.
Home product stainless steel stainless steel 430 stainless steel 430 grade 430 is a ferritic, straight chromium, nonhardenable grade, combining good corrosion resistance and formability characteristics with useful mechanical properties. Cracking of stainless steel nozzle sleeve metallurgical. Stress corrosion cracking international institute of. Investigation of stress corrosion cracking of austenitic, duplex and. Stress corrosion cracking in a brewery paul mueller company. This paper presents a fusion welding process that was developed for snf canister repair.
To understand the corrosion resistance properties of duplex stainless steel, you must also understand the concept of stress corrosion cracking. A 1970 study initiated by the national bureau of standards nbs, now known as the national institute of standards and technology nist, buried over 6000 corrosion coupons or specimens of stainless steel types 201, 202, 301, 304, 316, 409, 410, 430, and 434. Corrosion rates of different alloys in dry chlorine and temperature c at which given rates are exceeded are presented in the table below. Its mechanical properties enable its structures to remain extremely resistant to rust. Duplex stainless steel has become more and more popular for its combination of strength and affordability. If the stainless steel is going to be subjected to heat treatment, it is important to know how the various grades of stainless steel. A nickelfree, 17% chromium ferritic stainless steel originally designed for. Chloride stress corrosion involves selective attack of a metal along its grain boundaries. Stress corrosion cracking of an austenitic stainless steel in. How to reduce the risk of stress corrosion cracking scc the risk of stress corrosion cracking scc can be minimized through plant and equipment design. Pitting corrosion of a stainless steel is illustrated in the figure 1. Ferritic stainless steel 434 plate s43400 ferritic. By adding molybdenum, the corrosion resistance is increased. Although no stainless steel grade is totally immune to chloride scc, the relative resistance of stainless steels.
Austenitic stainless steel has a thermal conductivity of one third of. Postweld heat treatment to avoid stress corrosion cracking. Alloy 434 is one of the most widely used of the ferritic stainless steels. Sensor requirements for detection and characterization of. Corrosion resistance of stainless steels corrosion in concrete corrosion problems are not limited to outside surfaces. Failure analysis of corrosion on stainless steel fasteners. Stress corrosion cracking resistance of grade 430 is very high, as it is for all ferritic grades. Types and grades of stainless steel plate stainless plate. Paper presented at stainless steel world 2005 conference, maastricht, the netherlands, 810 november 2005. For the moly ferritic stainless steels, the corrosion resistance is a function of the chromium and molybdenum contents. In addition, ferritic grades are very resistant to stress corrosion cracking scc.
The bolts exhibited corrosion predominantly on the head of the bolt around the set screw, underneath the head of the bolt, and in the threads. It also increases the scaling resistance at elevated temperatures. On the socalled linear polarization method for measurement. In common with the other ferritic stainless steels, the moly ferritics are not susceptible to stress corrosion cracking scc. Stress relieved samples were uniaxially prestrained to 5% and were loaded with nine levels of mgcl 2, investigating cl. Ferritic and duplex stainless steels are immune to stress corrosion cracking because the ferrite phase. Corrosion resistance of type 444 ferritic stainless steel in acidic chloride media. Normally 50 deg c but can occur at lower temperatures around 25 deg c in specific environments, notably swimming pools. Exposure to room temperature environment showed parabolic weight loss behaviour, with corrosion rates of up to 0.
It also provides good heat and oxidation resistance up to 1500f as well as good mechanical properties. Ferritic stainless steel an overview sciencedirect topics. Benchtype corrosion tests were run using synthetic hf process waste solutions and boiling 65% hnosub 3. Corrosion assisted fatigue cracking of a 316l stainless steel nozzle sleeve from a chemical processing vessel summary. More elaborate experiments are described under benchscale and plant conditions. Intergranular stress corrosion cracking of welded steel twi. Tp304 ss and tp316 ss can occur when water containing chloride is present underneath insulation, external metal skin temperature exceeds approximately 50 c, and there is no surface protection or when the protective coating e. The 17% cr 434 steel alloys have good corrosion resistance to atmospheric. Stainless steels are ironbase alloys containing 10.
Higher naoh concentrations and exposure temperatures resulted in a reduced stability of the electrochemical passivity domain. Chloride stress corrosion cracking in austenitic stainless. Here we tell you differences between various stainless steel alloy. Webcorr provides corrosion consultancy services, corrosion expert witness and corrosion short courses for inhouse training, online and distance learning. When specifying stainless steels, common names like 304 can be used but it is important to also list the specific unified numbering system uns designation for the specific alloy. Mti received five stainless steel bolts from a marine environment. It occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions and high temperature. Duplex stainless steel is a combination of ferritic and austenitic steels, resistant to pitting, stress corrosion cracking, and crevice attack. To address the risk of stress corrosion cracking scc in pool. Austenitic stainless steel, which is usually referred to as the 300 series, is ideally suited to laser welding, table 4.
The addition of molybdenum improves the alloys general corrosion resistance and makes the alloy resistant to attack. Paul woollin twi ltd, granta park, great abington, cambridge, cb1 6al, uk. Penn stainless inventory now includes alloy 430 uns s43000 in sheet, sheet coil, plate, round bar, processed flat bar and tubular products. Ferritic steels are highchromium, magnetic stainless steels that have a low carbon content. Moly ferritics corrosion resistance stainless steel. Stress corrosion cracking scc is a common issue with many specialty alloys. Stress corrosion cracking scc can slowly destroy your brewery equipment without warning. Scc is often associated with chlorides, but can also occur with caustics and other corrosive media. Pdf chloride induced stress corrosion cracking of type.
Pdf corrosion resistance of type 444 ferritic stainless. The series is nonmagnetic, not heat treatable and has good formability. The thin but dense chromium oxide film which forms on the surface of a stainless steel provides corrosion resistance and prevents further oxidation. Nishimura 1 material engineering division, government industrial research institute, chugoku hirosuehiro, 222, kure, hiroshima, 73701, japan. There are five types of stainless steels depending on the other. Not only can duplex stainless steel hold up reliably through trauma impact, but through corrosion as well. Chloride stress corrosion cracking in austenitic stainless steel is characterized by the multibranched lightning bolt transgranular crack pattern. Stainless steel provides both strength and corrosion resistance inside the concrete, providing a long, maintenancefree service life of the structure. Outokumpu core 434 41 is a 1% molybdenumalloyed ferritic stainless steel with medium chromium and normal carbon content, which can be used in many corrosive environments, such as at the cold end of automotive exhaust systems.
A precursor of stress corrosion cracking in chloridebearing environments is pitting corrosion, occurring if the stainless steel is not sufficiently resistant to pitting. Stress corrosion cracking scc is the main corrosion failure mode for 310s stainless steel. Chloride stress corrosion cracking clscc is a type of stress corrosion cracking scc and is one of the most well known forms of scc in the refining and chemical processing industries. These steels are magnetic but cannot be hardened or strengthened by heat treatment. They have high corrosion resistance due to high chromium content of about 430%. Ferritic steels, types 430 and 434, are resistant to scc in mgcl2 at 140c.
The pitting corrosion resistance of the alloy 444 was studied by means of immersion tests and electrochemical. This article outlines and explains what is ferritic stainless steel. Stress corrosion cracking scc of duplex stainless steel. Chloride induced stress corrosion cracking of type 304 and 304l stainless steels in air article pdf available in zairyotokankyo 523. Chloride stress corrosion cracking clscc is one the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. Stainless steel comparator alloying elements following is a list of alloying elements found in stainless steels and their functions. Modes such as pitting, crevice, stress corrosion cracking, sulfide stress corrosion cracking, integranular, galvanic, contact, passivation and pickling are covered. Scc in a 316 stainless steel chemical processing piping system. The micrograph below x300 illustrates scc in a 316 stainless steel chemical processing piping system.
Your tanks are the core of your brewery, so it is important to understand what scc is, what causes it, and what to do when your tanks suffer from this type of damage. Chloride stress corrosion cracking scc of type 304 and 304l austenitic stainless steels ss was studied by a constant load method in air at a temperature of 353 k with relative humidity rh of. They are classified in to three types such as ferritic, austenitic, and martensitic steels based on their crystalline structure. Stresscorrosion cracking of aisi 4340 steel in aqueous environments article pdf available in metallurgical and materials transactions a 422.
Stresscorrosion cracking of aisi 4340 steel in aqueous. Residual stress is produced by initial metal forming and welding operations although a good welding procedure will avoid this problem by properly annealing the heated area. The addition of molybdenum improves the alloys general corrosion resistance and makes the alloy resistant to attack by deicing chemicals. The potential for stress corrosion cracking scc of welded stainlesssteel interim storage containers for spent nuclear fuel snf has been identified as a high priority data gap. Ferritic stainless steels are plain chromium stainless steels with a chromium content varying between 10. Chloride stress corrosion cracking inspectioneering. Scc can occur typically in hot water tanks or swimming pools. Effects of cerium on the inclusions and pitting corrosion behavior of.